ࡱ> ^a]_ 1bjbj kV5\5\m)$>>>Pd4>O,&ZOk+++++++$-0`+{{{+ ,!!!{0+!{+!!V(@v)rZ( +,0O,(x11v)v)1)0{{!{{{{{++{{{O,{{{{1{{{{{{{{{> :  CHEM. 232 (ORGANIC I) SYLLABUS Fall 2015 ̽ Office hours: Michael C. Cann MWF 10:00-10:50 Office LSC 495 W 3:00-3:50 Phone: (570) 941-7519 e-mail:  HYPERLINK "mailto:michael.cann@scranton.edu" michael.cann@scranton.edu web page:  HYPERLINK "http://www.scranton.edu/faculty/cannm/" http://www.scranton.edu/faculty/cannm/ Organic I is the first in a two semester sequence of courses designed to introduce you to and provide you with 1) a solid background in the structural theory, reactions, and mechanisms of reactions in organic chemistry, 2) the fundamentals of green chemistry and in particular the concept of atom economy, and 3) an introduction to the concept of sustainability. In this course we will emphasize the understanding and rationalization of concepts and theories in organic chemistry - not memorization. Each chapter in organic chemistry builds on the knowledge from the previous chapter and if you get off to a slow or poor start in this course you will have a very difficult time. Objectives Upon completion of this course you will be able to: recognize and name the major functional groups write systematic names for molecules draw accurate structures for molecules draw and understand the stereochemical relationships of molecules correlate molecular structure with physical properties correlate molecular structure with chemical properties (predict reactions, derive syntheses) categorize reactions by type recognize and understand the reactions and properties of cation, anion and radical intermediates write reaction mechanisms correlate energy changes with molecular structure changes use IR spectra to determine information about the structures of molecules recognize the structures and functions of the main classes of biomolecules understand the basic premise of green chemistry use the concept of atom economy to help measure the efficiency of a reaction understand the basics of the concept of sustainability and how chemists can facilitate sustainable development In order for you to succeed in achieving the course objectives you must: attend class regularly read the text before the corresponding class meeting digest (in small bites), understand and apply each concept and theory before moving on take an active part in class; answer and ask questions work through all the suggested problems as soon as we have discussed the material in class work through additional textbook problems particularly if you are having difficulty with the material make lists of concepts and problems you don't understand and bring your list to my office it is also strongly recommended that you sign up for a tutor It is imperative that you constantly keep up with the material, come to class, and during class you concentrate on the subject matter. In order to facilitate this: 1) Attendance will be taken on a daily basis. You are allowed up to six absences after which your semester grade will be dropped by one full letter grade per absence. Arriving late is considered an absence. 2) There will likely be several unannounced 20 point quizzes during the semester. 3) Use of electronic equipment such as computers, cell phones, ipads, head phones, ipods, etc., during class and tests is not allowed unless permission is granted by the instructor. If you are having difficulty with this course (or any other course), get help! Help can be obtained in many ways including: 1) See me! If you cant make my office hours, see me after class and we can set up a time to meet. email me:  HYPERLINK "mailto:michael.cann@scranton.edu" michael.cann@scranton.edu or call me (941-7519) . If Im not in, leave a message on my voice mail and Ill get back to you ASAP. Helping students learn is my job and I really enjoy my job so please bother me! 2) There are tutors available at the Center for Teaching & Learning Excellence (941- 4038), these tutors are upper-class students who have been handpicked by the LRC for their ability in organic chemistry and their willingness to help and to teach. This is a free service! There is also group tutoring I will keep you posted about this. 3) Talk to your fellow students and set up study groups. If you are either a student who is doing well or poorly and would like to get involved in a study group, give me your name and I will try to facilitate this. Whatever you do, you must take the initiative! Dont wait, as soon as you see a problem, get help! But remember there is no substitute for good, hard work. Textbook: Solomons, T. W. Graham, Fryhle, C., and Snyder, S. A., Organic Chemistry, 11th Edition, John Wiley and Sons, Inc., 2014. Examinations and Grading: Three one period examinations, worth 100 points each, several quizzes (20 pts. each) and one comprehensive final examination, worth 200 points, will be given. On each hourly exam and the final, you will receive a numerical grade and a letter grade. The letter grade will be based on a curve for my two sections of organic. At the end of the semester the numerical total of the period exams, the final exam, and the quizzes will be placed on a curve and semester grades will be assigned. The final will be a comprehensive exam covering the entire semester. In borderline cases, your semester grade will be influenced by your class participation or lack thereof. No exams will be dropped and no makeup exams will be given. If you miss an exam or a quiz and you have a valid excuse, your semester grade will be based on the remaining exams and quizzes. Otherwise, you will receive a 0 on the exam (quiz). Homework problems will be suggested, but will neither be collected nor graded. If you would like to discuss your answers (or questions), please see me. Academic Code of Honesty: Conduct that violates the ̽ Academic Code of Honesty includes plagiarism, duplicate submission of the same work, collusion, providing false information, unauthorized use of computers, theft & destruction of property, & unauthorized possession of tests & other materials. For this course you are required to read complete Academic Code of Honesty. Please see the link at  HYPERLINK "http://www.scranton.edu/academics/wml/acad-integ/index.shtml" http://www.scranton.edu/academics/wml/acad-integ/index.shtml Violation of the ̽ Academic of Honesty in this course, will generally result in a 0 or F for the assignment/test and may result in an F for the semester. Students with Disabilities: In order to receive appropriate accommodations, students with disabilities must register with the Center for Teaching and Learning Excellence and provide relevant and current documentation. Students should contact Mary Ellen Pichiarello (570-941-4039, LSC 580) or Dr. Andre Catalfamo (570-941-4218, LSC 582E) for an appointment. For more information, please visit  HYPERLINK "http://www.scranton.edu/disabilities" http://www.scranton.edu/disabilities. Writing Center Services: The Writing Center focuses on helping students become better writers. Consultants will work one-on-one with students to discuss students work and provide feedback at any stage of the writing process. Scheduling appointments early in the writing progress is encouraged. To meet with a writing consultant, call (570) 941-6147 to schedule an appointment, or send an email with your available meeting times, the course for which you need assistance, and your phone number to:  HYPERLINK "mailto:writing-center@scranton.edu" writing-center@scranton.edu. Online appointments are also available connecting virtually using HYPERLINK "http://www.scranton.edu/academics/ctle/writing/GOOGLE.PDF"Google Docs and Google Talk. CHAPTERS AND TENTATIVE EXAM DATES Chapter Topic Exam 1 The Basics: Bonding and Molecular Structure 2 Families of Carbon Compounds Acids and Bases, An Introduction to Organic Reactions and their Mechanisms In conjunction with section 3.1 read/download the Introduction to Green Chemistry,  HYPERLINK "http://www.scranton.edu/faculty/cannm/green-chemistry/english/intro.shtml" \t "_blank" www.scranton.edu/faculty/cannm/green-chemistry/english/intro.shtml the module and PowerPoint presentation at  HYPERLINK "http://www.scranton.edu/faculty/cannm/green-chemistry/english/organic.shtml" \t "_blank" www.scranton.edu/faculty/cannm/green-chemistry/english/organic.shtml (in this module you may skip the section that is labeled optional). 4 Nomenclature and Conformations of Alkanes and Cycloalkanes #1 Fri., 9/25/15 5 Stereochemistry: Chiral Molecules 6 Ionic Reactions: Nucleophilic Substitution and Elimination Reactions of Alkyl Halides #2 Fri., 10/23/15 7 Alkenes and Alkynes I. Properties and Synthesis; Elimination Reactions of Alkyl Halides 8 Alkenes and Alkynes II. Addition Reactions 10 Radical Reactions #3 Mon., 11/30/15 (Return from break) FINAL EXAMINATION Final Exam Week 12/8-12 SUGGESTED PROBLEMS Chapter 1 5-8, 10-19, 22-25, 31, 33, 34, 35 (omit o, p), 36, 37, 43, 44, 49 Chapter 2 2-10, 12, 15, 17, 18, 20- 22, 25, 27, 29-33, 35, 36,43-48, 52 Chapter 3 1-4, 7, 9, 10, 13-18, 20, 22-24, 26, 27, 30, 32, 33, 35 Introduction to Green Chemistry ( HYPERLINK "http://www.scranton.edu/faculty/cannm/green-chemistry/english/intro.shtml" www.scranton.edu/faculty/cannm/green-chemistry/english/intro.shtml ) 1, 2, 3, 4, 5 Green Module for Organic Chemistry ( HYPERLINK "http://www.scranton.edu/faculty/cannm/green-chemistry/english/organicmodule.shtml" www.scranton.edu/faculty/cannm/green-chemistry/english/organicmodule.shtml ) 1a,b, 3 Chapter 4 1-8, 10-13, 15-22, 23 (omit m, n), 24 (omit e, h), 26, 33, 36, 37, 41, 43, 46 Chapter 5 1-30, 32, 33 a- d, 34, 36, 38, 40 (omit m, q) add conformational and cis-trans to choices, 42 add conformational and cis-trans to choices, 46, 47, 49, 50 Chapter 6 1-24, 25 (omit d), 27, 28 (omit d, e, f, h, l), 29 (omit h), 30-35, 38, 46 Chapter 7 1, 2, 4-15, 17, 18, 19 (omit a), 20-22, 23 dont refer to retrosynthesis, 26, 27, 28 (omit f), 29-33, 34 (omit d), 35-41, 43, 44 (omit c), 45-47 Chapter 8 1-4, 6-9, 11, 13, 15, 20-36, 38-40, 46-48, 51, 53, 54 Chapter 10 1, 6- 9, 10a ,b, 11-13, 14 dont do retrosynthesis,, 19-21, 22 (omit e,f), 23, 25, 29 (omit g), 30 (omit f)     PAGE 4 *-G  ! 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Cann Normal.dotmMichael Cann5Microsoft Office Word@`4<@JB@@.?#՜.+,D՜.+,@ hp  ̽KX)  TitleH 8@ _PID_HLINKSABXZRhttp://www.scranton.edu/faculty/cannm/green-chemistry/english/organicmodule.shtmlPYJhttp://www.scranton.edu/faculty/cannm/green-chemistry/english/intro.shtml'?Lhttp://www.scranton.edu/faculty/cannm/green-chemistry/english/organic.shtmlPYJhttp://www.scranton.edu/faculty/cannm/green-chemistry/english/intro.shtml]G:http://www.scranton.edu/academics/ctle/writing/GOOGLE.PDF&R#mailto:writing-center@scranton.eduP\ %http://www.scranton.edu/disabilitiesI =http://www.scranton.edu/academics/wml/acad-integ/index.shtmlE$!mailto:michael.cann@scranton.edu(!'http://www.scranton.edu/faculty/cannm/E$!mailto:michael.cann@scranton.edu  !"#$%&'()*+-./012356789:;<=>?@ABCDEFGHIJKLNOPQRSTVWXYZ[\_`cRoot Entry FvbData ,1Table4+1WordDocument kVSummaryInformation(MDocumentSummaryInformation8UMsoDataStorep=SrYSGQB3P0LEYA==2p=SrItem  PropertiesUCompObj r   F Microsoft Word 97-2003 Document MSWordDocWord.Document.89q